图书介绍
伏安原理 英文PDF|Epub|txt|kindle电子书版本网盘下载
- 纪效波，克雷格·班克斯（CraigEBanks）编著 著
- 出版社： 北京：化学工业出版社
- ISBN：9787122181497
- 出版时间：2014
- 标注页数：265页
- 文件大小：40MB
- 文件页数：273页
- 主题词：伏安法－英文
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图书目录
1 Equilibrium Electrochemistry1
1.1 Chemical Equilibrium1
1.2 An Introduction to Electrochemical Equilibrium5
1.3 Electron Transfer at the Solution|Electrode Interface6
1.4 The Nernst Equation and Electrode|Solution Interfaces8
1.4.1 One Phase to Another8
1.5 Reference Electrodes19
1.6 Standard Electrode Potentials22
1.7 Formal Potentials26
References27
2 Electrode Kinetics29
2.1 Introduction to Dynamic Electrochemistry29
2.2 Experimental Arrangement30
2.3 Electron Transfer and Energy Levels32
2.4 Electrode Kinetics33
2.5 The Tafel Law38
2.6 Introduction to Marcus Theory40
References46
3 Cyclic Voltammetry47
3.1 Introduction47
3.2 Diffusion50
3.2.1 The Nernst Diffusion Layer53
3.3 Migration54
3.4 Electrode-Solution Interface55
3.5 Electrode Kinetics57
3.6 Reaction Mechanisms68
3.7 pH Effects77
3.8 Voltammetry at Microelectrodes78
3.9 Chronoamperometric Experiments:Determining the Electro-catalytic Rate Constant87
3.10 EC' Mechanism at a Microdisc Electrode89
3.11 ECE Mechanism at a Microdisc Electrode90
3.12 Effect of Temperature on Steady-state Currents at a Microdisc91
3.13 Properties of Microelectrodes91
3.14 Applications of Microelectrodes92
3.15 Microelectrode Arrays94
3.16 Graphitic and Related Electrode Surfaces103
3.17 Voltammetry at Heterogeneous Surfaces109
3.18 Thin Layer Effects from Modifying Electrodes120
References124
4 Hydrodynamic Techniques127
4.1 Introduction to Convection127
4.2 Rotating Disc Systems128
4.3 Channel and Tubular Electrodes139
4.4 High Speed Channel Electrode145
4.5 Hydrodynamic Electrodes Based on Impinging Jets150
References154
5 Electroanalysis156
5.1 Introduction to Electroanalysis156
5.2 Square Wave Voltammetry156
5.3 Stripping Voltammetry158
5.4 Sono-electroanalysis161
5.5 Screen Printed Sensors168
5.6 Bismuth Modified Electrodes182
5.7 Relevant Analytical Parameters184
References187
6 Carbon Electrochemistry189
6.1 Introduction189
6.2 Carbon Nanotubes189
6.3 Graphene Electrochemistry202
6.3.1 Electrochemistry of heterogeneous graphitic surfaces206
6.3.2 Fundamental electrochemistry of graphene209
6.3.3 Graphene as a heterogeneous electrode surface210
6.3.4 Effect of surfactants on the electrochemistry of graphene218
6.3.5 Metallic impurities on the electrochemistry of graphene219
6.3.6 Direct electro-catalysis219
6.3.7 Graphene Oxide(GO)223
References227
7 Energy Storage and Generation230
7.1 Introduction230
7.2 Super-and Ultra-Capacitors231
7.3 Testing Super-and Ultra-Capacitors238
7.4 CycleLife239
7.5 Graphene Based Supercapacitors240
7.6 Hybrid Super-or Ultra-Capacitors245
7.6.1 Noble Metal Oxides246
7.6.2 Asymmetrical Supercapacitors249
7.7 Fuel Cells250
7.7.1 Graphene Based Fuel Cells255
7.7.2 Microbial Bio-fuel Cells258
7.7.3 Enzymatic Bio-fuel Cells260
7.8 Batteries/Li-ion Batteries260
References263