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INORGANIC REACTION MECHANISMS AN INTRODUCTIONPDF|Epub|txt|kindle电子书版本网盘下载

INORGANIC REACTION MECHANISMS AN INTRODUCTION
  • JOHN O. EDWARDS 著
  • 出版社： INC.
  • ISBN：
  • 出版时间：1964
  • 标注页数：190页
  • 文件大小：44MB
  • 文件页数：203页
  • 主题词：

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图书目录

Chapter 1 INTRODUCTION1

1-1 The Subject of this Book1

1-2 Stoichiometry2

1-3 Equilibria3

1-4 Reaction Rate5

1-5 Transition-State Theory8

1-6 Order and Reaction Mechanism10

1-7 Symbols11

Chapter 2 BINDING STRENGTH AND REACTION RATES:ACIDS,BASES,AND SOLVENTS14

2-1 Bronsted Theory14

2-2 Specific-Acid Catalysis15

2-3 General-Acid Catalysis17

2-4 Bronsted Equation18

2-5 Statistical Corrections20

2-6 Lewis Theory22

2-7 Other Definitions24

2-8 General Influence of Solvents25

2-9 Physical Properties of Solvents26

2-10 Chemical Nature of Solvents28

Chapter 3 BINDING STRENGTH AND REACTION RATES:LINEAR FREE-ENERGY RELA-TIONS31

3-1 Linear Free-Energy Relations32

3-2 Assumptions36

3-3 Mathematical Form37

3-4 Examples of LFER37

3-5 Problems with LFER40

3-6 Intermediates45

3-7 Kinetic Isotope Effects46

Chapter 4 NUCLEOPHILIC DISPLACEMENTS51

4-1 Types of Mechanism51

4-2 Rate Scales53

4-3 Rate Factors54

4-4 Orders of Nucleophilic Character57

4-5 Displacements on Phosphorus59

4-6 Displacements in Planar Complexes63

4-7 Discussion68

Chapter 5 NONRADICAL MECHANISMS FOR PEROXIDE REACTIONS73

5-1 Nucleophilic Displacements73

5-2 Peroxyanions as Nucleophiles81

5-3 Peroxyanions as Leaving Groups82

5-4 Peroxide Decomposition84

5-5 Hypohalite Reactions88

Chapter 6 REPLACEMENTS IN OCTAHEDRAL COMPLEXES90

6-1 Labile and Inert Complexes90

6-2 Crystal-Field Stabilization92

6-3 General Aspects95

6-4 Dissociation vs．Displacement100

6-5 Base Hydrolysis103

6-6 Chromium(Ⅲ)Compounds107

6-7 Complexes of Divalent Cations112

Chapter 7 ELECTRON-TRANSFER REACTIONS OF COMPLEXES115

7-1 Electron-Transfer Theory115

7-2 Outer-Sphere Exchange Reactions118

7-3 Bridge Mechanism120

7-4 Iron(Ⅱ)—Iron(Ⅲ)Exchange125

7-5 Two-Electron Transfers127

7-6 Noncomplementary Reactions128

7-7 Replacement through Redox Mechanism132

Chapter 8 REACTIONS OF OXYANIONS137

8-1 Factors Affecting Rates137

8-2 Oxygen Exchange142

8-3 Exchange between Phosphate and Water145

8-4 Induced Reactions146

8-5 Chromate-Arsenite Reaction149

8-6 Urea-Formation Reaction151

Chapter 9 FREE RADICAL REACTIONS154

9-1 Steady-State Approximation155

9-2 Decomposition of Persulfate155

9-3 Dinitrogen Pentoxide Decomposition158

9-4 Chain Reactions160

9-5 Hydrogen-Bromine Reaction163

9-6 Other Hydrogen-Halogen Reactions166

9-7 Persulfate-Peroxide Reaction170

Chapter 10 SOME UNSOLVED PROBLEMS174

10-1 General Problems174

10-2 Constituents of a Rate Law175

10-3 Trace-Metal Catalysis176

10-4 Problems in Phosphorus Displacements177

10-5 Replacements in Coordination Compounds180

10-6 Nitrosation Reactions181

10-7 Some Reactions to Study183

Index185

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