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聚合物的表征 英文PDF|Epub|txt|kindle电子书版本网盘下载
- （美）布伦德尔，（美）埃文斯，（美）周主编 著
- 出版社： 哈尔滨：哈尔滨工业大学出版社
- ISBN：9787560342849
- 出版时间：2014
- 标注页数：319页
- 文件大小：52MB
- 文件页数：339页
- 主题词：聚合物－研究－英文
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图书目录
POLYMER STRUCTURES AND SYNTHESIS METHODS1
1.1 Introduction1
1.2 Chain Structures in Natural and Synthetic Polymers1
The Nature of Polymeric Materials1
The Composition of Polymeric Materials3
Molecular Weight and Its Distribution11
Polymer Chain Configurations12
Polymer Chain Conformations14
Polymer Solid-State Structure,Morphology,and Transitions15
Polymer Surface Structure18
1.3 Polymer Synthesis20
Chain Reaction Polymerization21
Coordination Polymerization24
Step Reaction Polymerization25
1.4 Summary26
POLYMER FABRICATION TECHNIQUES28
2.1 Introduction28
2.2 Processing Techniques29
Foam Processing31
Film-Forming Processes31
Composites32
Extrusion34
Molding35
Coatings36
Other Methods37
2.3 Applications37
Development of Spray-On Insulation for the Thermal Protection System of the External Tank in the Space Shuttle Program37
Development of Thick,Thin,and Ultrathin Polyimide Films40
Langmuir-Blodgett(L-B)Films47
Polymer Composites49
Molding Processes55
Fiber Drawing and Surface Modification Processes56
CHEMICAL COMPOSITION OF POLYMERS65
3.1 Introduction65
3.2 Chemical Composition:Questions to Ask66
3.3 Techniques for Determination of Chemical Composition:What to Use to Ask the Questions67
3.4 Illustrative Examples of Characterization of Chemical Composition of Polymers72
Stoichiometry72
Functionality73
Phase Separation80
Surface Modification81
Interfacial Chemical Composition83
Impurities83
3.5 Summary:New Horizons86
CHARACTERIZATION OF THE MORPHOLOGY OF POLYMER SURFACES,INTERFACES,AND THIN FILMS BY MICROSCOPY TECHNIQUES92
4.1 Overview of Polymer Interfaces and Thin Films92
4.2 Introduction to Microscopy Techniques93
4.3 Optical Microscopy94
4.4 Scanning Electron Microscopy98
Low-Voltage High-Resolution Scanning Electron Microscopy100
Environmental Scanning Electron Microscopy104
4.5 Transmission Electron Microscopy106
4.6 Scanning Probe Microscopy111
4.7 New Microscopies116
STRUCTURE AND MORPHOLOGY OF INTERFACES AND THIN FILMS BY SCATTERING TECHNIQUES121
5.1 Introduction121
5.2 Industrial Applications122
Adhesion122
Biomedical Applications124
Langmuir-Blodgett Films and Other Thin Films125
5.3 Integrated Optics Method127
Wave-Guiding127
Nonlinear Optical Method130
5.4 Reflectivity136
5.5 Grazing Incidence X-Ray Scattering139
SURFACE THERMODYNAMICS150
6.1 Introduction150
6.2 Theory of Wetting,Spreading,and Adhesion151
6.3 Experimental Methods154
Contact Angles154
Adsorption and Calorimetry157
Inverse Gas Chromatography162
Infrared(FTIR)Spectroscopy164
SURFACE MODIFICATION OF POLYMERS169
7.1 Introduction169
7.2 Wet-Chemical Modification of Polymer Surfaces171
Surface Roughening and Seeding in Placing Operations171
Surface Treatment for Bondability173
Surface Treatment Using Adhesion Promoters175
Surface Modification by Photochemical Methods177
7.3 Dry Modification Techniques179
Modification by High-and Low-Energy Ion Beams179
Plasma Modification of Polymer Surfaces187
Other Dry Treatment Techniques191
7.4 Summary192
ADHESION198
8.1 Introduction198
8.2 Physical Meaning of Adhesion200
8.3 Theoretical Analysis of Adhesion200
8.4 Experimental Measurement of Adhesion203
8.5 Standardization of Test Procedure205
8.6 Locus of Failure205
8.7 Key Adhesion Issues207
8.8 Illustrative Examples208
8.9 Summary209
CHEMISTRY,REACTIVITY,AND FRACTURE OF POLYMER INTERFACES215
9.1 Introduction215
9.2 Polyimide Structure and Properties218
9.3 Polymer-Polymer Interfaces222
9.4 Metal-Polymer Interfaces224
9.5 Polymer-Metal Interfaces230
9.6 Thermal Stress and Interfacial Fracture234
THE POLYMER-POLYMER INTERFACE244
10.1 Introduction244
10.2 Techniques for Measuring Diffusion Distances Much Greater Than Molecular Size247
10.3 Techniques for Measuring Concentration Profiles on the Order of Molecular Size252
10.4 Summary259
FRICTION AND WEAR(TRIBOLOGY)262
11.1 Introduction262
11.2 Basic Concepts263
11.3 Tribological Applications264
11.4 Mechanisms of Friction and Wear265
Friction266
Wear268
11.5 Correlation of Properties with Friction and Wear269
Energy-to-Rupture and Abrasive Wear269
Cohesive Energy and Abrasive Wear271
Ratio of Applied Stress to Failure Strength and Wear271
Molecular Weight and Wear271
Crystallinity and Wear273
Loss Tangent and Friction273
Closure274
11.6 Measurement of Friction and Wear274
ASTM Laboratory Tests276
Designing Laboratory Tests284
11.7 Reporting and Interpretation of Measurements291
11.8 Summary293
REFERENCES FOR FUTURE STUDY295
Index311